Hydrogen gas: Difference between revisions
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== | ==Energy storage basics== | ||
For [[energy storage]] of renewable electricity: | |||
* Hydrogen gas would be '''produced''' via ''electrolysis'': | |||
* | ** Electricity is used to convert water (H<sub>2</sub>O) into hydrogen gas and oxygen gas. | ||
* Hydrogen gas would be '''consumed''' via... | |||
** Burning it as fuel, producing heat. | |||
** Using it in ''fuel cells'', producing electricity {{light|(and still some heat)}}. | |||
** {{light|In both cases, the hydrogen reacts with oxygen in the air to form H<sub>2</sub>O again (water vapor).}} | |||
This process has more energy losses than charging/discharging a battery, but hydrogen gas is far better suited for '''long-term''' energy storage. Hydrogen can be stockpiled in pressurized tanks (if designed properly). It can also be [[transportation of hydrogen gas|shipped]] long distances, just like any other fuel. This could help in cases where renewable energy sources are geographically far away from where energy is needed. | |||
Hydrogen fuel | The intent would be for hydrogen gas to be used in place of [[fossil fuels]]: | ||
* Cars, trucks, etc. would be: | |||
** [[Hydrogen combustion vehicles]], or | |||
** [[Hydrogen fuel cell electric vehicles]] | |||
* Homes & buildings: | |||
** For [[heating]]: Hydrogen gas could be burned instead of [[natural gas]]. | |||
** For cooking food: Hydrogen gas could probably work with gas stoves. {{rn}} | |||
* Factories: | |||
** Most of the energy used in manufacturing is in the form of high heat needed for processing materials. Factories could burn hydrogen gas instead of burning [[coal]] or natural gas. | |||
== | ==Energy sources== | ||
'''Main use-case:''' Storing [[wind]] power.<br /> | |||
Here's why: | |||
* Wind power is far more intermittent than [[solar]]. Whereas solar follows a day/night cycle, windy and not-so-windy seasons can last for ''months'' at a time. | |||
* Wind turbines tend to be geographically far away from where electricity is needed, on average. Wind power is more spread out in terms of [[land]], compared to the same amount of energy from local [[rooftop solar]]. Hydrogen could be transported long distances that can't be reached with power lines. | |||
== | '''Other use-case:''' Since solar panels produce more energy in the summer, it would still be worthwhile to store ''some'' of that energy via hydrogen gas, to be used during the winter. {{light|Note, however: Batteries are a better choice for smoothing out the ''day/night cycle'' of solar power.}} | ||
{{sum| | '''Other use-case:''' Storing energy from [[hydroelectricity]] during long periods of low demand. | ||
<!-- TODO: find number to fill this in with: | |||
For renewables & hydrogen to replace all fossil fuels, hydrogen production & consumption would have to scale up by about ___ times the status quo. | |||
--> | |||
==Status quo== | |||
* Most hydrogen today is '''produced''' from [[fossil fuels]] ([[natural gas]]) via [//wikipedia.org/wiki/Steam_reforming steam reforming]. The carbon emissions are as high as burning the natural gas itself. | |||
* Most hydrogen today is '''used''' in producing [[fertilizer]]. | |||
==Platinum-group metals== | |||
{{sum|Problem in some cases}} | |||
Both '''electrolysis''' and '''fuel cells''' need platinum-group metals (PGMs): | Both '''electrolysis''' and '''fuel cells''' need platinum-group metals (PGMs): | ||
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* Since vehicle fuel cells use the biggest share of PGMs in this estimate, this is yet another reason to advocate for [[public transit]] and [[walkability]]. | * Since vehicle fuel cells use the biggest share of PGMs in this estimate, this is yet another reason to advocate for [[public transit]] and [[walkability]]. | ||
</div></tab></tabs> | </div></tab></tabs> | ||
<!-- TODO: Uncomment this when done writing about PGMs above (a more immediate and important mention that should be on here first) | <!-- TODO: Uncomment this when done writing about PGMs above (a more immediate and important mention that should be on here first) | ||
==Atmospheric losses== | |||
{{sum|Probably minor}} | {{sum|Probably minor}} | ||
The concern would be that when hydrogen gas leaks to the atmosphere, it's so light that it ends up being lost into outer space via [//wikipedia.org/wiki/Jeans_escape Jeans escape]. At what point would this permanent loss of hydrogen affect ecosystems? Would it be on the scale of billions of years or millions of years or thousands? Per unit of energy, I bet there would actually be hydrogen loss than with [[nuclear fusion]]. {{rn}} {{pn|TODO: Estimate using the status-quo gas leak rate of natural gas.}} }} | The concern would be that when hydrogen gas leaks to the atmosphere, it's so light that it ends up being lost into outer space via [//wikipedia.org/wiki/Jeans_escape Jeans escape]. At what point would this permanent loss of hydrogen affect ecosystems? Would it be on the scale of billions of years or millions of years or thousands? Per unit of energy, I bet there would actually be hydrogen loss than with [[nuclear fusion]]. {{rn}} {{pn|TODO: Estimate using the status-quo gas leak rate of natural gas.}} }} | ||
--> | --> | ||
==Energy losses== | |||
{{sum|Lossy but manageable}} | |||
* Electrolysis is at most 80% efficient. | |||
* Fuel cells are at most 60% efficient. | |||
* Thus, best-case ''electricity'' recovery is only 48%{{x|in other words, 60% of 80%}}. Far less than most batteries which have a charge-discharge efficiency of 80% to 90%. | |||
** But for things that just need ''heat'', then the energy recovery is still a good 80%. For example, wind power to produce hydrogen gas to burn for heating homes. | |||
*** Note however: For vehicles, this is outweighed by the fact that [[hydrogen combustion vehicles]] are less fuel-efficient than [[fuel cell vehicles]]. | |||
{{pn|TODO: add calculation: knowing the losses, is there still enough [[land]] for wind-generated hydrogen gas were to directly replace all fossil fuels, in principle?}} | |||
==Shelf life== | |||
{{sum|{{rn}} }} | |||
Chemically, hydrogen is the lightest gas (smallest molecules). This makes it harder to store than other gases, but there are still ways. {{en}} | |||
==Pipelines== | |||
{{sum|{{rn}} }} | |||
Could existing natural gas pipelines be used for transporting hydrogen gas? Or would it cause too much leakage/corrosion? {{rn}} | |||
==Safety== | |||
{{sum|Manageable}} | |||
* Just like natural gas, hydrogen gas is non-toxic and odorless but highly flammable. For safety in consumer applications, small quantities of some non-toxic but smelly gas{{x|such as methyl mercaptan, hydrogen sulfide, or ethyl isobutyrate (Wikipedia has a page "Hydrogen odorant")}}should be added to it, so that people would know if there's a gas leak. | |||
* {{pn|This section needs more safety-related info.}} | |||
==Color terminology== | ==Color terminology== | ||
Hydrogen is a colorless gas, but | Hydrogen is a colorless gas, but researchers sometimes ''name'' it with colors to indicate ''how it was produced'': | ||
* "Grey hydrogen" is made from natural gas (steam reforming) - high [[greenhouse gas]] emissions. Currently the vast majority of hydrogen is produced this way. | * "Grey hydrogen" is made from natural gas (steam reforming) - high [[greenhouse gas]] emissions. Currently the vast majority of hydrogen is produced this way. | ||
* "Blue hydrogen" is made from natural gas the same way, but with [[carbon capture]]. This is ''supposed'' to reduce emissions, but ''in practice'' it doesn't help much.<!-- TODO: cite that article I found awhile ago --> | * "Blue hydrogen" is made from natural gas the same way, but with [[carbon capture]]. This is ''supposed'' to reduce emissions, but ''in practice'' it doesn't help much.<!-- TODO: cite that article I found awhile ago --> | ||
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<!-- | <!-- | ||
SCRAP: Not sure where to put this | SCRAP: Not sure where to put this, if anywhere at all: | ||
===Production from fossil fuels=== | ===Production from fossil fuels=== | ||
Currently most hydrogen is produced from [[natural gas]] via [//wikipedia.org/wiki/Steam_reforming steam reforming], but this emits just as much CO<sub>2</sub> as burning the natural gas itself. | Currently most hydrogen is produced from [[natural gas]] via [//wikipedia.org/wiki/Steam_reforming steam reforming], but this emits just as much CO<sub>2</sub> as burning the natural gas itself. | ||
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There's another (similar) process called [[methane cracking]] which takes in natural gas, and produces hydrogen gas + solid carbon (not CO<sub>2</sub>). The main problem is that it's a ''net loss'' of energy {{x|it takes a lot more energy than you ultimately get by burning the hydrogen gas}}. In theory, it doesn't have to be. | There's another (similar) process called [[methane cracking]] which takes in natural gas, and produces hydrogen gas + solid carbon (not CO<sub>2</sub>). The main problem is that it's a ''net loss'' of energy {{x|it takes a lot more energy than you ultimately get by burning the hydrogen gas}}. In theory, it doesn't have to be. | ||
{{p|Chemistry equations:<br />CH<sub>4</sub> → C + 2 H<sub>2</sub>   (endothermic: 75 kJ/mol)<br />2 H<sub>2</sub> + O<sub>2</sub> → 2 H<sub>2</sub>O (exothermic: 572 kJ/mol)}} | {{p|Chemistry equations:<br />CH<sub>4</sub> → C + 2 H<sub>2</sub>   (endothermic: 75 kJ/mol)<br />2 H<sub>2</sub> + O<sub>2</sub> → 2 H<sub>2</sub>O (exothermic: 572 kJ/mol)}} | ||
--> | --> | ||
==See also== | |||
* [[Methane cracking]] {{light|- another way to produce hydrogen gas. Not worthwhile currently, but ''in theory'' the right tech could maybe change that.}} |
Revision as of 17:17, 28 October 2023
- Not to be confused with nuclear fusion of hydrogen atoms.
Hydrogen gas (H2) is a combustible fuel that leaves behind nothing but water vapor (H2O) when burned.
There are no natural resources of hydrogen gas
This page is about how hydrogen gas could be used with renewable energy.
Energy storage basics
For energy storage of renewable electricity:
- Hydrogen gas would be produced via electrolysis:
- Electricity is used to convert water (H2O) into hydrogen gas and oxygen gas.
- Hydrogen gas would be consumed via...
- Burning it as fuel, producing heat.
- Using it in fuel cells, producing electricity (and still some heat).
- In both cases, the hydrogen reacts with oxygen in the air to form H2O again (water vapor).
This process has more energy losses than charging/discharging a battery, but hydrogen gas is far better suited for long-term energy storage. Hydrogen can be stockpiled in pressurized tanks (if designed properly). It can also be shipped long distances, just like any other fuel. This could help in cases where renewable energy sources are geographically far away from where energy is needed.
The intent would be for hydrogen gas to be used in place of fossil fuels:
- Cars, trucks, etc. would be:
- Homes & buildings:
- For heating: Hydrogen gas could be burned instead of natural gas.
- For cooking food: Hydrogen gas could probably work with gas stoves. [RESEARCH needed]
- Factories:
- Most of the energy used in manufacturing is in the form of high heat needed for processing materials. Factories could burn hydrogen gas instead of burning coal or natural gas.
Energy sources
Main use-case: Storing wind power.
Here's why:
- Wind power is far more intermittent than solar. Whereas solar follows a day/night cycle, windy and not-so-windy seasons can last for months at a time.
- Wind turbines tend to be geographically far away from where electricity is needed, on average. Wind power is more spread out in terms of land, compared to the same amount of energy from local rooftop solar. Hydrogen could be transported long distances that can't be reached with power lines.
Other use-case: Since solar panels produce more energy in the summer, it would still be worthwhile to store some of that energy via hydrogen gas, to be used during the winter. Note, however: Batteries are a better choice for smoothing out the day/night cycle of solar power.
Other use-case: Storing energy from hydroelectricity during long periods of low demand.
Status quo
- Most hydrogen today is produced from fossil fuels (natural gas) via steam reforming. The carbon emissions are as high as burning the natural gas itself.
- Most hydrogen today is used in producing fertilizer.
Platinum-group metals
Both electrolysis and fuel cells need platinum-group metals (PGMs):
- [platinum, palladium, rhodium, ruthenium, iridium, osmium]
- Any of these metals will do, but all of them are extremely scarce (even more than gold), with platinum & palladium being the most available.
- These metals serve as catalysts in the reactions. They are not used up, but they need to be there, in a thin layer plated onto the electrodes.
Note: It is possible to build fuel cells and electrolysis systems without PGMs, but the energy-efficiency is much lower.[QUANTIFICATION needed] There are scientists trying to overcome this,[LINKS needed] but there's no guarantee that it will be viable in the near future.
How much would be needed, if hydrogen were scaled up?
The mass of PGMs needed is proportional to peak power:
- For electrolysis systems, the maximum rate of hydrogen production is limited by the amount of PGMs.
- For fuel cell vehicles, the horsepower is limited by the amount of PGMs.
- But the vehicle can still achieve short bursts of higher horsepower if there's a battery or supercapacitor in parallel with the fuel cell.
Last updated in 2023
www.carsguide.com.au › car-advice › how-many-cars-are-there-in-the-wor...
hedgescompany.com › blog › 2021/06 › how-many-cars-are-there-in-the-...
https://www.heraeus.com/media/media/hpm/doc_hpm/precious_metal_update/en_6/20181031_PGM_Market_Analysis.pdf
But ThermoFisher (which is more reputable, perhaps) says "The recoverable amounts of Pt, Pd, and Rh in each [vehicle] can range from 1-2 grams for a small car to 12-15 grams for a big truck in the US." - Are There Precious Metals in Catalytic Converters? https://www.thermofisher.com/blog/metals/platinum-group-metal-recovery-from-spent-catalytic-converters-using-xrf/
I assume they mean 1-2 grams ''total'', not 1-2 grams ''of each'' Pt Pd Rh, right? That would make sense considering they also mention that the ratios vary as metal prices/availability change over time.
1 to 2 grams total recoverable is also consistent with the following study: Yakoumis et al 2018 IOP Conf. Ser.: Mater. Sci. Eng. 329 012009 - Real life experimental determination of platinum group metals content in automotive catalytic converters - https://iopscience.iop.org/article/10.1088/1757-899X/329/1/012009/pdf
Still no word on what percentage this ''recoverable'' is of total PGMs - how efficient is the recycling process? Unknown
Source: USGS Mineral Commodity Summaries 2021
Source: USGS Mineral Commodity Summaries 2021
Platinum-group metal reserves worldwide by country 2021
Statista - https://www.statista.com › statistics › platinum-me...
Data source:
Manufacturing Cost Analysis for Proton Exchange Membrane Water Electrolyzers
August 2019 Technical Report NREL/TP-6A20-72740
https://www.nrel.gov/docs/fy19osti/72740.pdf
Pages 4 and 5: Table 1:
Cell plate area: CCM coated area: 748 cm^2
Platinum loading (anode): 7 g/m^2
Platinum-iridium loading (cathode): 4 g/m^2
Single cell power: 1965 W
From this we can calculate:
(7 g/m^2 + 4 g/m^2)/2 * 748 cm^2 / 1965 W = 0.20936387 g/kW
Sucks that the article doesn't directly specify this 'g/kW' value for us to confirm whether my calculations are correct. Still this is the best data source I could find. The article does also provide a lot of specs on total costs (ranging from $561/kW all the way down to $69/kW for some proposed systems with advanced techniques and economies of scale).
https://css.umich.edu/factsheets/wind-energy-factsheet
- This is per megawatt capacity (peak), not per average output.
- Stats can vary tremendously based on how windy the location is.
- This stat is based on 172 different wind projects scattered throughout the USA.
- Consider variance: (34.5 +/- 22.4) hectares/MW
- This is the total land use, including the spacing between turbines in a wind farm.
- This is much bigger than [wind.rq_land_disturbed] which is just the land directly impacted by constructing the turbine itself.
Citation:
Land-Use Requirements Of Modern Wind Power Plants In The United States
(Paul Denholm, Maureen Hand, Maddalena Jackson, and Sean Ong)
Page 16
Does not include the fuel used in generating electricity. See [energy.tes] for that.
Citation: "Key World Energy Statistics 2020" IEA
- Page 47 - Simplified energy balance table - World energy balance, 2018
- page 47: World energy balance, 2018
- - Total Energy Supply (TES), first 4 columns combined
www.carboncommentary.com › blog › hydrogen-made-by-the-electrolysis...
Suppose,
- that all of today's energy demand were to be met using hydrogen gas
- that all hydrogen gas were to be produced using wind power (or something with the same capacity factor as wind)
- that all PGMs can forever be recovered and recycled
Tl;dr: There are enough PGM minerals in the Earth, but today's mining rates would be far too slow.
We'd have to start mining a lot faster, and find some way to do it without exploitative labor. [ELABORATION needed]
Calculations: PGMs needed for hydrogen production: (calculation loading)
PGMs needed for hydrogen-based electricity consumption: (calculation loading)
PGMs recoverable from catalytic converters of old gas cars:Old semi trucks (not counted here) could also provide a bit more (calculation loading)
Compared to mineral reserves: (calculation loading)
Compared to current production rate: (calculation loading)
This estimate is imperfect and oversimplified, but probably reasonable in a scenario where some vehicles use hydrogen combustion and some use fuel cells. In general,
- If more vehicles use hydrogen combustion, we'd need more wind power but less PGM.
- If more vehicles use fuel cells, we'd need less wind power but more PGM.
In any case, producing that much wind power is maybe reasonable if most farmland were to be covered in wind turbines. (calculation loading)
More musings about the calculations above:
- Hydrogen combustion vehicles are about as energy-efficient as gasoline combustion vehicles. But hydrogen fuel cell vehicles are more efficient. We'd need less hydrogen than this estimate calls for.
- Home electricity would be done with fuel cells too. We'd need more PGMs than this estimate. We'd need more hydrogen than this estimate, to make up for the losses in fuel cells (although those losses could be used as heating in some cases).
- If electric semi trucks use fuel cells too, we'd need more PGMs than this estimate.
- Or if a large enough percent of all vehicles use combustion instead of fuel cells, then we'd need less PGM than this estimate.
- We didn't count the hydrogen needed in the vehicles that transport the hydrogen (hopefully would be minor, like with fossil fuel transport).
- All this is based on status-quo energy demand, which relies on the fact that most of the world currently lives in poverty. If all nations were developed, a lot more resources would be needed.
- Wind power land estimates are based on status-quo installations which are likely on windier-than-average land. In which case, maybe crop land wouldn't be enough - but then again, there's also pasture and barren land that could be used.
- But in any case, we probably wouldn't actually use wind/hydrogen for everything anyway. Rooftop solar combined with batteries could probably be a better way to provide electricity whenever hydrogen need not be involved.
- Since vehicle fuel cells use the biggest share of PGMs in this estimate, this is yet another reason to advocate for public transit and walkability.
Energy losses
- Electrolysis is at most 80% efficient.
- Fuel cells are at most 60% efficient.
- Thus, best-case electricity recovery is only 48%
(...)( in other words, 60% of 80% ) . Far less than most batteries which have a charge-discharge efficiency of 80% to 90%. - But for things that just need heat, then the energy recovery is still a good 80%. For example, wind power to produce hydrogen gas to burn for heating homes.
- Note however: For vehicles, this is outweighed by the fact that hydrogen combustion vehicles are less fuel-efficient than fuel cell vehicles.
- But for things that just need heat, then the energy recovery is still a good 80%. For example, wind power to produce hydrogen gas to burn for heating homes.
TODO: add calculation: knowing the losses, is there still enough land for wind-generated hydrogen gas were to directly replace all fossil fuels, in principle?
Shelf life
Chemically, hydrogen is the lightest gas (smallest molecules). This makes it harder to store than other gases, but there are still ways. [ELABORATION needed]
Pipelines
Could existing natural gas pipelines be used for transporting hydrogen gas? Or would it cause too much leakage/corrosion? [RESEARCH needed]
Safety
- Just like natural gas, hydrogen gas is non-toxic and odorless but highly flammable. For safety in consumer applications, small quantities of some non-toxic but smelly gas
(...)( such as methyl mercaptan, hydrogen sulfide, or ethyl isobutyrate (Wikipedia has a page "Hydrogen odorant") ) should be added to it, so that people would know if there's a gas leak. - This section needs more safety-related info.
Color terminology
Hydrogen is a colorless gas, but researchers sometimes name it with colors to indicate how it was produced:
- "Grey hydrogen" is made from natural gas (steam reforming) - high greenhouse gas emissions. Currently the vast majority of hydrogen is produced this way.
- "Blue hydrogen" is made from natural gas the same way, but with carbon capture. This is supposed to reduce emissions, but in practice it doesn't help much.
- "Pink hydrogen" is made from electrolysis using nuclear energy.
- "Green hydrogen" is made from electrolysis using renewable energy.
See also
- Methane cracking - another way to produce hydrogen gas. Not worthwhile currently, but in theory the right tech could maybe change that.